In this current experimental research, the amount of improvement in the thermal conductivity of HEC hybrid epoxy resins was studied by adding copper oxide nanoparticles CuONp and carbon nanotubes (CNTs) as hybrid additives in different proportions to select the sample with the highest thermal conductivity value to include it in the design of the Flat Plate Solar Collector FPSC as Thermal Interface Material TIM reduces thermal resistance between the absorber plate and the tube. Four groups of samples were prepared using a mass balance with a sensitivity of 0.01g and a magnetic mixing device, then poured into cubic plastic molds to take the shape of the sample. The first group consists of one sample of pure epoxy to calibrate the thermal properties testing device through it. The second group consists of five samples of epoxy loaded with CNTs by weight (1, 3, 5, 7.5, 10) %. The third group consists of five samples of epoxy loaded with CuONp with weight percentages of (1, 3, 5, 7.5, 10) %. The fourth group consists of five samples of epoxy loaded with CuONp and CNTs combined in weight percentages of (1, 3, 5, 7.5, 10) %. The thermal conductivity of the samples was measured experimentally using the hot disk analyzer technique to measure thermal specifications. After comparing the thermal conductivity values of the samples, the highest value was 1.57 W/mK for the HEC sample loaded with 10% CNTs, which represents 9.23 times higher than pure epoxy
The Organo modified and unmodified sodium montmorillonite clay effect on thermal and mechanical properties of the waste low density polyethylene (wLDPE) were studied. Commercialize unmodified (MMT) and Organo-modified clay (OMMT) were added to the wLDPE to prepare wLDPE-clay noncomposites by melt intercalation method. OMMT and MMT were added in a range of 1-5 wt %. Fourier transform infrared spectroscopy (FTIR) used to evaluate polymer structure before and after the fabrication. Thermogravimetric analysis (TGA) and Differential Scanning Calorimetry (DSC) were used to analyse the thermal stability and thermal properties for the wLDPE and fabricated nanocomposites. Tensile mechanical characteristics of the waste specimens before and after nanocompsite fabrication were evaluated. The FTIR exhibited no change in the chemical structure of the wLDPE used after clay addition. Melting temperature and crystallization percentage were increased up to 1 wt% loaded and decreased in with clay content increasing when compared to the original waste matrix. The thermal steadiness of the wLDPE /clay nanocomposites were found enhanced in the case of loading 3 wt% of OMMT. The elastic modulus has improved in the 3% OMMT loaded.
Temperature distribution through asphalt and the underlying layer have been obtained numerically using finite element method where a varying induced heat from sun and environment cause fluctuating temperature distribution throughout .The maximum effect of these parameters on the temperature of the asphalt is expected in summer, so the temperature distribution was studied in the summer only. Some interesting results were found ; at tropical zone such as in Baghdad the asphalt surface temperature may reach (70 C ) and it is reduced with depth .Due to fluctuating environment heat effect, the subsequent temperature of the asphalt and the underlying layer may fluctuating with some delay and damping depending on the layers thermal properties , these result may be used later to predict both the erosion rate of car tiers and asphalt thickness, also the preserved energy using asphalt layer may be used to confined heat for further usage as in electrical generation.
Addition of 40% of Phosphogypsum ( Pg ) and Cement Klin dust ( CKD) to Asphalt has given encouraging results including penetration , softening , Flash point an fire point identical to the accepted properties of industrial asphalt. Chlorination of Natural Asphalt at 1.5 hr the same additive of 40% in the presence of Fe2O3 as catalyst have affered optimizing rhealogy and thermal properties. The FT-IR and UV identifications have indicated the existence of clear groups as aresult of chlorination and additives. The microscopic study for floor samples have shown the good atomic distribution to floor asphalt .Generalty results on the modified natural asphalt ( Heet- Abo- Aljeer ) have proved the capability of using it in paving instead of Industrial asphalt .